My physics is probably off, but wouldn't less coffee mean that there's more energy from the water available to overcome the osmotic pressure of the less desirable compounds in each granule? My understanding, which might be wrong, is that the good compounds get extracted first at low energies, and too much energy, such as with a high temperature, or to
o much time, will start to extract oleic acid and other undesirables. If my coffee had bad tastes but wasn't too 'strong' I would consider adding more grounds and keeping the energy content ( water volume, temp and brew time) the same. Worth trying out in extremes to see what the general trends are at least.
Well, to the best of my knowledge, kind of. Think of the coffee as a granular filter affected by the grain size of the coffee. That is, what does affect extraction -- from nanoscale physics, to chemistry, to coffee -- is surface area to volume ratio. You're physically acting on a much greater volume by using a finer grind as more and more surface area is exposed to water. Having said all that, transit time for the fluid is important too since longer extraction times simply mean that the lower solubility compounds have more time to be extracted.
To use espresso as an example: given equal temperatures and extraction times, a coarse versus espresso grind gives entirely different results.