1) Goldeneye, by a good margin, serious tone and unique bad guy, tank sequence, Famke and Isabella both radiant, etc
2) Tomorrow Never Dies, fun to rewatch, great bike scene, Teri looks great/great chemistry with Pierce, Michelle kicked tail while also showing good chemistry later on with Pierce
....
3, tentatively) Die Another Day, between the absurdly over-the-top special effects, MTV editing, and Halle not only looking like she's afraid to break a nail during the action sequences but also seemed to be lacking any real spark with Pierce (mind, I like Halle in some other stuff, but not here)
And to this day I've never gotten around to the other one, I guess that would be the one with Denise as the nuclear scientist...I really should get around to it though see if it places 3rd or 4th.