You need to take higher resolution screenshots.
I'm not sure what to say, DLSS clearly does better details, like the number plate, preserves texture resolution better, such as the rocks and ground clutter, handles fine geometry better as the already mentioned fence, and has less (but still some) of the issues that PSSR occasionally has like noise and flickering. Especially noise, which plagues a lot of titles.
You can say PSSR perhaps does tree foliage better, although even that is up in the air. DLSS once again better with the fine detail preservation, but PSSR is doing a much better job of cleaning up the aliasing. So it's not a 100% DLSS win, but certainly not anything like 50/50.
That being said, all this is comparing DLSS 3.5 which got superseded by 3.7, then 4, and now 4.5.
Remedy patched the game PS5 Pro version of the game so that users can switch back to FSR because so many people were complaining. And again, Sony is heavily investing in PSSR2 with the work done on FSR4, because they are well aware that the first version simply doesn't hold up.