Now that I'm off work I wanted to make a list of some of my favorite games. I'll add clips where I can. I didn't include RE4 or Village because those are a given.
In no particular order.
The Foglands - Roguelite with an engaging story, it feels more like an action/adventure w/ roguelite elements. It's considered one of the worst games and it kind of was at launch but it was greatly cleaned up and man it's so good if you learn and engage with the mechanics. The movement speed and freejump/platforming are the best on PSVR2 IMO. Tons of variety in combat, tons of exploration. I don't recommend this if you don't have your VR sea legs though. Foglands is best when you're running and jumping and engaging with the chaotic nature of the gameplay. Standing around and pew pew pewing does not make this game shine.
Max Mustard - This is the indie Astrobot and it's insanely impressive. Hands down the best pure platformer on the headset.
Happy Funland - Walking sim that places you in an abandoned Disney World. The humor is dark and actually funny. Combat is janky as hell but it's a total afterthought and doesn't happen often. You're there to admire the artstyle, laugh, and ride rides.
Into the Radius - Awesome STALKER clone, VRAF in the best of ways and it looks fantastic on the headset. An absolute must-own if you like shooters and survival horror mechanics. A ton of gameplay options too, you can make it easy as hell or crank it up to brutal levels. It has something for everyone.
Genotype - Insanely impressive Metroid clone with a sprinkling of survival horror elements; limited inventory and when you die, you go back to your last save. Buttery smooth gameplay and crisp visuals.
Bulletstorm VR - This game was a complete mess at launch but the developers actually managed to fix everything and even added in new content, horde mode. Looks damn good in the headset and is a really fun campaign. I never played it on PS3/360, really cool to experience it in VR for a first playthrough.
Propagation: Paradise Hotel - For me, this is hands down the scariest game for PSVR2. You essentially get an indie version of REmake. Total classic-era survival horror gameplay. It looks great and plays even better. Sound is taken into account and they translated it to opening doors and drawers. You will be closing that door so gently, like you're 16 and sneaking back inside on a saturday night, and it's smooth as hell. It's insanely immersive and that's a big part of why it's so damn terrifying. It's relatively short, 5-6 hours but man, you will be glad when it's over. The adrenaline dumps this game gave me were on a level I'd never experienced before. I would have to sit down due to exhaustion at the end of each session.
Hubris - Great sci-fi FPS campaign. It's like you either love this game or don't like it. I really don't know why anyone wouldn't enjoy it but 100% to each their own. Fun shooting, good pacing, climbing, swimming. This game has great use of swimming and underwater combat. Looks great in the headset.
Moss 1&2 - Absolutely charming and fun as hell adventure game. It's third-person, kind of overhead in a way. Two absolute must-own games IMO.
Red Matter 2 - I actually think RM1 & 2 are a touch overrated. The 2nd is infinitely better than the first when it comes to gameplay though. I truly believe the aiming/shooting misaligned in RM2 but there's only a handful of combat sections and they aren't hard to get through. The game is all puzzles but it looks damn good in the headset and the jetpack you get is awesome. Boosting around and admiring the visuals is a total joy. This is also a great game for getting your sea legs because you're never at risk of dying and you can take the game at your own pace. It also uses physics to great effect. Stacking stuff up in VR can be fun as hell. My first time playing, I spent like 30 minutes tossing a boot into a laundry cart. Like I was playing bags/cornhole.
Cactus Cowboy: Desert Warfare - This game honestly might have the best FPS campaign on PSVR2. It's a solo-developed game with crude graphics. You play as a Special Ops Cactus fighting a war against bugs. The voice acting is AI. It sounds dumb as hell and it is but the gunplay and overall gameplay is so damn good. Incredibly impressive game. Even the credit crawl in the main menu is done well. The banter between the cacti's as the credits scroll is hilarious.
Organ Quarter - My personal favorite VR title. This was a PCVR kickstarter game from 2017. Total shoestring budget, team of 3 people. 1 guy did programming, 1 guy did the art, 1 guy did the music. It's basically a mix of RE 1996 and Silent Hill in VR. It's so damn good, legimately one of the best classic-style survival horror games ever made IMO. Not VRAF whatsoever, more like someone took a PSX survival horror title and slapped a VR mod on it.
Runner - Essentially the highway motorcycle scene from Akira in VR, while shooting guns and swinging a plasma sword. Procedurally generated levels, awesome soundtrack, one of the characters is voiced by the guy who did Spike in Cowboy Bebop. It's the best bang for your buck on the PSN store IMO.
There are a ton of others but of the 89 games I have in my library, those games in particular really stand out to me and I can always go back to them. You just recently got a headset right? If so, my humble advice is to not rely solely on YouTube and Reddit for reviews. Please believe that so many games get roasted, sometimes rightfully so, but many of these games get fixed with patches and no new reviews come out. I can't stress how chill the PSVR2 community is on gaf. Make this your first stop for impressions on games you're interested in.
edit- How could I forget Legendary Tales. Souls/Diablo style game, 4 player coop (or solo), physics based combat DONE RIGHT. This game is a freaking dime and an absolute must-own if that sounds like something up your alley and you have some friends to play with. I would gladly coop some Legendary Tales. It is a total riot with friends.