I have my doubts the second image is from the PS5 for a multitude of reasons....
but the main reason is that after processing each image and skipping back and forth, the image doesn't really move, as though the only difference is the fog cover from a 1-3 frame offset, which after processing makes the second image slightly better and less over sharpened at the end but effectively identical images other than that. The cynic in me says the odds of getting both systems within even 5frames of each other by non faceoff Pros like DF in a game running a 60fps looks highly suspicious, and I didn't even know you had any AMD cards, let alone a RX6900, and that before truly considering any of the other reasons I didn't feel the image was probably from a PS5.
What's the deal? How did you align the games on two different systems with two different frame-rates and slightly different rendering and get them almost on the same frame and so close they almost overlap pixel for pixel?