I got my PSVR during work today, and got it set up a couple hours ago.
So far I've tried four games:
Rez Infinite - First thing I booted up after getting it hooked together, and it's really just fantastic. Good game to check out the PSVR screens with too; overall the image reminds me a lot of the Vive. Good colors and brightness. Lack of lens artifacts is appreciated here. Only played through the first two stages. Head aiming makes this even more enjoyable in my opinion. Going to savor this one.
Battlezone - Spent only a few minutes in this one. I just wanted to see how it looked and felt mostly. Wasn't bothered by the movement in this one at all. Resolution of the screen hurts a bit here but overall is a decent looking title. Really interested to find a few other people and jump in here co-op.
Thumper - This game is really gorgeous in VR. If you already have a PC VR headset and are thinking you aren't going to get a PSVR, make sure you get this game when it shows up on Steam. First level was pretty easy but I can tell from the thread that it gets crazy. As expected this and Rez are my early favorites.
Batman VR - Tried to do this standing and the tracking sucks balls so far. Both on the Move and the headset. Visually the game looks pretty nice and I might continue on with this seated, but the standing experience leaves a little too much to be desired. Shut it off for now to spare my senses the disorientation.
Batman was my first run with the Move controllers and the best way I can describe their performance is that in the moments when they are working right, they're kind of like Vive controllers stuck in reprojection. Have a feeling I am going to be leaning towards seated / DS4 based VR games for PSVR. If you own a Rift or a Vive and are already keeping your expectations low in this aspect going into PSVR, I'd probably lower them a little further still.
That said, the DS4 based games were all pretty slick and the headset itself when I was parked in my office chair was behaving just fine. Pretty comfortable as others have mentioned, though there is a lot of light bleed on the bottom (way more than with the Rift) that makes you wish you could pull the scope in even further.