I noticed this a while ago watching "Agents of Shield." It was the episode title "Yes Man" where Lorelei was seducing a bunch of men for her army with her powers. The problem I found with it was that ALL of the men she was seducing happened to be heterosexual, which given statistics is extremely unlikely they were all straight. I was even half-expecting a one-off gay-joke but neither happened.
It was a very terrible episode regardless.
Her powers might not really matter regarding sexuality. In Powers there was a character who could make men do whatever she wanted and when this was explained by a gay character he was "Especially gay men!"