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Iron Man was definitely the best Avenger and Spencer is retarded. Hawkye is the best avenger in this game too. No doubt about it.No arguments on Felicia.
Iron Man was the best Avenger in vanilla. Captain America had a ton of issues in vanilla which include no damage off of air throws, poor combo options in corner, more punishable shield slashes and more reliance on assists. Iron Man was a complete character in vanilla but outclassed by Magneto who was in the same archetype. Iron Man had high damaging combos, great ranged normals, solid zoning game, solid rushdown/mix ups, combos off of air throws and the best beam assist in the game. Just was a lot hard to play.
Also Hawkeye is in Ultimate so Captain might not be the best Avenger. Iron Man.. the jury is still out on him. He's so hot and cold. Thor is really good.
Spencer is stupid good in Ultimate, you will not get any argument from me there. He's top 10 minimum potential top 5, I can say that with confidence. One of the premier TOD characters in this game right now. As far as grown ass men go, Spencer is the alpha male. Just like with Zero, not a lot of people play Spencer so people aren't complaining about him yet.
This is my own list of surefire S tiers by the end of the game's life.
Spencer
Zero
Dr. Doom
Crimson Viper
Wesker
Magneto
Amateratsu